Download e-book for iPad: Terpenoids and Steroids: Volume 1 (SPR Terpenoids and by K H Overton

By K H Overton

ISBN-10: 085186256X

ISBN-13: 9780851862569

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Additional resources for Terpenoids and Steroids: Volume 1 (SPR Terpenoids and Steroids (RSC))

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C), 1969,2220. loo lo’ J . E. Baldwin and J. C. Swallow, Angew. Chem. Internat. , 1969, 8, 601. R. W. Murray and M. L. Kaplan, J . Amer. Chem. ,1969,91, 5 3 5 8 . 28 Terpenoih and Steroids by lead tetra-acetate followed by triphenylphosphine into carvacrol trifluoroacetate (138). '02 (103) - The xylene-sensitized photochemical addition of hydroxylic compounds (water or alcohols) to limonene has been described in further detail by Kropp. 2 : 1 mixture of cis- and trans-fl-terpineol (142a,b; R = H) is obtained on irradiation of an aqueous solution containing a trace of xylene, or the corresponding methyl ethers (142a,b; R = Me) when methanol is the solvent.

R. Shannon, J . Chem. (C), 1969,2220. loo lo’ J . E. Baldwin and J. C. Swallow, Angew. Chem. Internat. , 1969, 8, 601. R. W. Murray and M. L. Kaplan, J . Amer. Chem. ,1969,91, 5 3 5 8 . 28 Terpenoih and Steroids by lead tetra-acetate followed by triphenylphosphine into carvacrol trifluoroacetate (138). '02 (103) - The xylene-sensitized photochemical addition of hydroxylic compounds (water or alcohols) to limonene has been described in further detail by Kropp. 2 : 1 mixture of cis- and trans-fl-terpineol (142a,b; R = H) is obtained on irradiation of an aqueous solution containing a trace of xylene, or the corresponding methyl ethers (142a,b; R = Me) when methanol is the solvent.

S. Dreiding, Helv. Chim. Acta, 1970, 53, 495. A. W. , B, 1969, 29, 2348. S. P. Acharya, H. C. Brown, A. Suzuki, S. Nozawa, and M. Itch, J. Org. , 1969, 34, 3015. Terpenoidrs ana' Steroids 38 It has been found'46 that 2-thujene (209) (also called a-thujene) can readily be prepared by K0Bu'-DMSO-catalysed isomerisation of sabinene (208). l~~ rrans-sabinene hydrates [(210a) and (210b)l has been made from sabinene by the oxymercuration-demercuration p r o c e d ~ r e . ' ~This ~ is the first effective means of preparing the cis-isomer, earlier Grignard reactions leading predominantly to the other isomer.

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Terpenoids and Steroids: Volume 1 (SPR Terpenoids and Steroids (RSC)) by K H Overton


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